Water potential and aggregate size effects on contact angle and surface energy

Research output: Contribution to journalArticleResearchpeer review

Authors

External Research Organisations

  • Iowa State University
View graph of relations

Details

Original languageEnglish
Pages (from-to)383-393
Number of pages11
JournalSoil Science Society of America Journal
Volume68
Issue number2
Publication statusPublished - 2004

Abstract

Soil wettability affects hydrological processes like infiltration, percolation, preferential flow, and surface runoff. Wettability is related to the soil-water contact angle, which in turn depends on the solid surface free energy. Little is known, however, about contact angles and their dependence on soil water potential. The main objective of this study was therefore to investigate the dynamics of contact angle due to variation of the water potential. Aggregate fractions of 2- to 4-, 1- to 2-, and <1-mm diameter and corresponding homogenized material of a subcritical water repellent Orthic Luvisol were studied at water potentials of -1000, -154, -30, and -0.14 MPa. Wettability was assessed in terms of the advancing contact angle by the capillary rise method (CRM). Additionally, we calculated the surface free energy. Results showed, that the contact angle increased as water potential increased to a specific level. It was found for several soil samples, that above this water potential level, the contact angle decreased again. The change of contact angle due to variation of water potential reached nearly 90° for one sample. Contact angles of homogenized fractions were slightly larger than those measured for the aggregate surfaces. Surface free energy was consistently between 55 and 65 mJ m-2 with relative contributions of the dispersion and polar components to surface free energy of approximately 1/3 and 2/3, respectively. We conclude, that the assessment and physical description of the specific water potential for which a surface becomes wettable is a key factor for a better understanding of soil wetting.

ASJC Scopus subject areas

Cite this

Water potential and aggregate size effects on contact angle and surface energy. / Goebel, Marc O.; Bachmann, Joerg; Woche, Susanne K. et al.
In: Soil Science Society of America Journal, Vol. 68, No. 2, 2004, p. 383-393.

Research output: Contribution to journalArticleResearchpeer review

Download
@article{61c4890ac2db4e14a93b38e02baf87c0,
title = "Water potential and aggregate size effects on contact angle and surface energy",
abstract = "Soil wettability affects hydrological processes like infiltration, percolation, preferential flow, and surface runoff. Wettability is related to the soil-water contact angle, which in turn depends on the solid surface free energy. Little is known, however, about contact angles and their dependence on soil water potential. The main objective of this study was therefore to investigate the dynamics of contact angle due to variation of the water potential. Aggregate fractions of 2- to 4-, 1- to 2-, and <1-mm diameter and corresponding homogenized material of a subcritical water repellent Orthic Luvisol were studied at water potentials of -1000, -154, -30, and -0.14 MPa. Wettability was assessed in terms of the advancing contact angle by the capillary rise method (CRM). Additionally, we calculated the surface free energy. Results showed, that the contact angle increased as water potential increased to a specific level. It was found for several soil samples, that above this water potential level, the contact angle decreased again. The change of contact angle due to variation of water potential reached nearly 90° for one sample. Contact angles of homogenized fractions were slightly larger than those measured for the aggregate surfaces. Surface free energy was consistently between 55 and 65 mJ m-2 with relative contributions of the dispersion and polar components to surface free energy of approximately 1/3 and 2/3, respectively. We conclude, that the assessment and physical description of the specific water potential for which a surface becomes wettable is a key factor for a better understanding of soil wetting.",
author = "Goebel, {Marc O.} and Joerg Bachmann and Woche, {Susanne K.} and Fischer, {Walter R.} and Robert Horton",
note = "Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2004",
doi = "10.2136/sssaj2004.3830",
language = "English",
volume = "68",
pages = "383--393",
journal = "Soil Science Society of America Journal",
issn = "0361-5995",
publisher = "Soil Science Society of America",
number = "2",

}

Download

TY - JOUR

T1 - Water potential and aggregate size effects on contact angle and surface energy

AU - Goebel, Marc O.

AU - Bachmann, Joerg

AU - Woche, Susanne K.

AU - Fischer, Walter R.

AU - Horton, Robert

N1 - Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2004

Y1 - 2004

N2 - Soil wettability affects hydrological processes like infiltration, percolation, preferential flow, and surface runoff. Wettability is related to the soil-water contact angle, which in turn depends on the solid surface free energy. Little is known, however, about contact angles and their dependence on soil water potential. The main objective of this study was therefore to investigate the dynamics of contact angle due to variation of the water potential. Aggregate fractions of 2- to 4-, 1- to 2-, and <1-mm diameter and corresponding homogenized material of a subcritical water repellent Orthic Luvisol were studied at water potentials of -1000, -154, -30, and -0.14 MPa. Wettability was assessed in terms of the advancing contact angle by the capillary rise method (CRM). Additionally, we calculated the surface free energy. Results showed, that the contact angle increased as water potential increased to a specific level. It was found for several soil samples, that above this water potential level, the contact angle decreased again. The change of contact angle due to variation of water potential reached nearly 90° for one sample. Contact angles of homogenized fractions were slightly larger than those measured for the aggregate surfaces. Surface free energy was consistently between 55 and 65 mJ m-2 with relative contributions of the dispersion and polar components to surface free energy of approximately 1/3 and 2/3, respectively. We conclude, that the assessment and physical description of the specific water potential for which a surface becomes wettable is a key factor for a better understanding of soil wetting.

AB - Soil wettability affects hydrological processes like infiltration, percolation, preferential flow, and surface runoff. Wettability is related to the soil-water contact angle, which in turn depends on the solid surface free energy. Little is known, however, about contact angles and their dependence on soil water potential. The main objective of this study was therefore to investigate the dynamics of contact angle due to variation of the water potential. Aggregate fractions of 2- to 4-, 1- to 2-, and <1-mm diameter and corresponding homogenized material of a subcritical water repellent Orthic Luvisol were studied at water potentials of -1000, -154, -30, and -0.14 MPa. Wettability was assessed in terms of the advancing contact angle by the capillary rise method (CRM). Additionally, we calculated the surface free energy. Results showed, that the contact angle increased as water potential increased to a specific level. It was found for several soil samples, that above this water potential level, the contact angle decreased again. The change of contact angle due to variation of water potential reached nearly 90° for one sample. Contact angles of homogenized fractions were slightly larger than those measured for the aggregate surfaces. Surface free energy was consistently between 55 and 65 mJ m-2 with relative contributions of the dispersion and polar components to surface free energy of approximately 1/3 and 2/3, respectively. We conclude, that the assessment and physical description of the specific water potential for which a surface becomes wettable is a key factor for a better understanding of soil wetting.

UR - http://www.scopus.com/inward/record.url?scp=1542380981&partnerID=8YFLogxK

U2 - 10.2136/sssaj2004.3830

DO - 10.2136/sssaj2004.3830

M3 - Article

AN - SCOPUS:1542380981

VL - 68

SP - 383

EP - 393

JO - Soil Science Society of America Journal

JF - Soil Science Society of America Journal

SN - 0361-5995

IS - 2

ER -

By the same author(s)