Wall-slip effects and their dependence on the recipe- and molecular-weight-induced compound viscosity

Research output: Contribution to journalArticleResearchpeer review

Authors

  • B. Klie
  • E. Schubert
  • U. Giese

External Research Organisations

  • German Institute of Rubber Technology (DIK e.V.)
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Details

Original languageEnglish
Pages (from-to)35-43
Number of pages9
JournalKGK Kautschuk Gummi Kunststoffe
Volume72
Issue number3
Publication statusPublished - Mar 2019
Externally publishedYes

Abstract

Employing a high-pressure capillary viscometer, this study investigates the flow behavior of rubber compounds as a function of compound viscosity. Test series are carried out with EPDM rubbers and additionally, the compound viscosity of a low-molecular-weight EPDM is selectively varied by admixing different concentrations of carbon black or oil so as to shed light on the influence of recipe-dependent viscosity on the wall-slip effect. The results show that the wall-slip effect increases as the recipe-dependent viscosity and the molecular weight of the raw polymer rise and that the critical wall shear stress indicating supercritical flow behavior is achieved even at lower shear rates.

Keywords

    Compound viscosity, EPDM, Highpressure capillary viscometer (HCV), Rheology, Rubber extrusion, Slip-stick, Wall slip

ASJC Scopus subject areas

Cite this

Wall-slip effects and their dependence on the recipe- and molecular-weight-induced compound viscosity. / Klie, B.; Schubert, E.; Giese, U.
In: KGK Kautschuk Gummi Kunststoffe, Vol. 72, No. 3, 03.2019, p. 35-43.

Research output: Contribution to journalArticleResearchpeer review

Download
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AU - Klie, B.

AU - Schubert, E.

AU - Giese, U.

PY - 2019/3

Y1 - 2019/3

N2 - Employing a high-pressure capillary viscometer, this study investigates the flow behavior of rubber compounds as a function of compound viscosity. Test series are carried out with EPDM rubbers and additionally, the compound viscosity of a low-molecular-weight EPDM is selectively varied by admixing different concentrations of carbon black or oil so as to shed light on the influence of recipe-dependent viscosity on the wall-slip effect. The results show that the wall-slip effect increases as the recipe-dependent viscosity and the molecular weight of the raw polymer rise and that the critical wall shear stress indicating supercritical flow behavior is achieved even at lower shear rates.

AB - Employing a high-pressure capillary viscometer, this study investigates the flow behavior of rubber compounds as a function of compound viscosity. Test series are carried out with EPDM rubbers and additionally, the compound viscosity of a low-molecular-weight EPDM is selectively varied by admixing different concentrations of carbon black or oil so as to shed light on the influence of recipe-dependent viscosity on the wall-slip effect. The results show that the wall-slip effect increases as the recipe-dependent viscosity and the molecular weight of the raw polymer rise and that the critical wall shear stress indicating supercritical flow behavior is achieved even at lower shear rates.

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