Details
| Original language | English |
|---|---|
| Pages (from-to) | 123-127 |
| Number of pages | 5 |
| Journal | Journal of molecular structure |
| Volume | 410-411 |
| Publication status | Published - 16 Jun 1997 |
| Externally published | Yes |
Abstract
The well-defined pore systems of crystalline microporous SiO2 modifications (porosils) can be used as templates for the ordered arrangement of inorganic guest species like iodine or the mercury halides. The systematic variation of the host structures, including pore systems from zero- to three-dimensional, allows interactions between the guest molecules in various directions to be controlled. Moreover, the periodic cage system of one of the porosils used, deca-dodecasil 3R, is well-suited as a crystalline matrix for the isolation of sulphur rings. The unique properties of these novel host-guest compounds are probed using spectroscopic techniques, including X ray absorption, UV/Vis and Raman spectroscopy.
Keywords
- Host-guest compounds, Porosils, Raman spectroscopy, UV/Vis spectroscopy, X-ray absorption spectroscopy
ASJC Scopus subject areas
- Chemistry(all)
- Analytical Chemistry
- Chemistry(all)
- Spectroscopy
- Chemistry(all)
- Organic Chemistry
- Chemistry(all)
- Inorganic Chemistry
Cite this
- Standard
- Harvard
- Apa
- Vancouver
- BibTeX
- RIS
In: Journal of molecular structure, Vol. 410-411, 16.06.1997, p. 123-127.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Spectroscopic investigations of novel host-guest compounds based on microporous SiO2 frameworks and inorganic guest species
AU - Wirnsberger, G.
AU - Fritzer, H. P.
AU - Van De Goor, G.
AU - Pillep, B.
AU - Behrens, Peter
AU - Popitsch, A.
N1 - Funding information: We thank the Deutsche Forschungsgemeinschaft, which has supported part of this work under contract Be 1664/l-2. Moreover, we want to express our thanks to the SRS Daresbury and the HASYLAB Hamburg for providing outstanding facilities during the measurements. The measurements in Daresbury were sponsored by the European Large Scale Facilities Programme.
PY - 1997/6/16
Y1 - 1997/6/16
N2 - The well-defined pore systems of crystalline microporous SiO2 modifications (porosils) can be used as templates for the ordered arrangement of inorganic guest species like iodine or the mercury halides. The systematic variation of the host structures, including pore systems from zero- to three-dimensional, allows interactions between the guest molecules in various directions to be controlled. Moreover, the periodic cage system of one of the porosils used, deca-dodecasil 3R, is well-suited as a crystalline matrix for the isolation of sulphur rings. The unique properties of these novel host-guest compounds are probed using spectroscopic techniques, including X ray absorption, UV/Vis and Raman spectroscopy.
AB - The well-defined pore systems of crystalline microporous SiO2 modifications (porosils) can be used as templates for the ordered arrangement of inorganic guest species like iodine or the mercury halides. The systematic variation of the host structures, including pore systems from zero- to three-dimensional, allows interactions between the guest molecules in various directions to be controlled. Moreover, the periodic cage system of one of the porosils used, deca-dodecasil 3R, is well-suited as a crystalline matrix for the isolation of sulphur rings. The unique properties of these novel host-guest compounds are probed using spectroscopic techniques, including X ray absorption, UV/Vis and Raman spectroscopy.
KW - Host-guest compounds
KW - Porosils
KW - Raman spectroscopy
KW - UV/Vis spectroscopy
KW - X-ray absorption spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=12644280826&partnerID=8YFLogxK
U2 - 10.1016/S0022-2860(96)09678-0
DO - 10.1016/S0022-2860(96)09678-0
M3 - Article
AN - SCOPUS:12644280826
VL - 410-411
SP - 123
EP - 127
JO - Journal of molecular structure
JF - Journal of molecular structure
SN - 0022-2860
ER -