Details
| Original language | English |
|---|---|
| Pages (from-to) | 175-183 |
| Number of pages | 9 |
| Journal | Journal of molecular structure |
| Volume | 833 |
| Issue number | 1-3 |
| Publication status | Published - 15 May 2007 |
Abstract
The high-resolution pure rotational spectra of CuI and AgI have been reinvestigated in the frequency range 2.5-18 GHz using microwave Fourier transform spectroscopy. Gaseous samples of the diatomic metal iodides have been obtained by laser ablation of target rods made of suitable solid precursors. Improved rotational parameters, nuclear quadrupolar coupling constants, and spin-rotation interaction constants have been obtained, along with the first reported spin-spin coupling parameters for copper iodide. Information about the anisotropy of nuclear magnetic shielding and the indirect spin-spin coupling in the absence of intermolecular effects are derived from the high-resolution rotational spectroscopic data.
Keywords
- Laser ablation, Nuclear shielding, Rotational spectroscopy, Spin-spin coupling
ASJC Scopus subject areas
- Chemistry(all)
- Analytical Chemistry
- Chemistry(all)
- Spectroscopy
- Chemistry(all)
- Organic Chemistry
- Chemistry(all)
- Inorganic Chemistry
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In: Journal of molecular structure, Vol. 833, No. 1-3, 15.05.2007, p. 175-183.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Hyperfine constants, nuclear magnetic shielding and spin-spin coupling parameters for AgI and CuI
AU - Bizzocchi, Luca
AU - Giuliano, Barbara M.
AU - Grabow, Jens Uwe
N1 - Funding Information: L.B. thanks the University of Bologna for financial support (Marco Polo Project). J.-U.G. gratefully acknowledges support from the Deutsche Forschungsgemeinschaft (DFG) and the Land Niedersachsen.
PY - 2007/5/15
Y1 - 2007/5/15
N2 - The high-resolution pure rotational spectra of CuI and AgI have been reinvestigated in the frequency range 2.5-18 GHz using microwave Fourier transform spectroscopy. Gaseous samples of the diatomic metal iodides have been obtained by laser ablation of target rods made of suitable solid precursors. Improved rotational parameters, nuclear quadrupolar coupling constants, and spin-rotation interaction constants have been obtained, along with the first reported spin-spin coupling parameters for copper iodide. Information about the anisotropy of nuclear magnetic shielding and the indirect spin-spin coupling in the absence of intermolecular effects are derived from the high-resolution rotational spectroscopic data.
AB - The high-resolution pure rotational spectra of CuI and AgI have been reinvestigated in the frequency range 2.5-18 GHz using microwave Fourier transform spectroscopy. Gaseous samples of the diatomic metal iodides have been obtained by laser ablation of target rods made of suitable solid precursors. Improved rotational parameters, nuclear quadrupolar coupling constants, and spin-rotation interaction constants have been obtained, along with the first reported spin-spin coupling parameters for copper iodide. Information about the anisotropy of nuclear magnetic shielding and the indirect spin-spin coupling in the absence of intermolecular effects are derived from the high-resolution rotational spectroscopic data.
KW - Laser ablation
KW - Nuclear shielding
KW - Rotational spectroscopy
KW - Spin-spin coupling
UR - http://www.scopus.com/inward/record.url?scp=33947308622&partnerID=8YFLogxK
U2 - 10.1016/j.molstruc.2006.09.018
DO - 10.1016/j.molstruc.2006.09.018
M3 - Article
AN - SCOPUS:33947308622
VL - 833
SP - 175
EP - 183
JO - Journal of molecular structure
JF - Journal of molecular structure
SN - 0022-2860
IS - 1-3
ER -