Guest-Induced Flexibility in a Multifunctional Ruthenium-Based Metal-Organic Framework

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Authors

  • Karen D.J. Hindricks
  • Volodymyr Bon
  • Oliver Treske
  • Adrian Hannebauer
  • Andreas Schaate
  • Yaşar Krysiak
  • Stefan Kaskel
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Details

Original languageEnglish
Pages (from-to)657-665
Number of pages9
JournalChemistry of materials
Volume36
Issue number2
Early online date3 Jan 2024
Publication statusPublished - 23 Jan 2024

Abstract

We present a new example of rare metal-organic frameworks (MOFs) containing ruthenium inorganic building units (IBUs). Advanced characterization techniques such as three-dimensional electron diffraction and in situ powder X-ray diffraction, performed in parallel with adsorption of various gases and vapors, were used to determine the structure and framework dynamics of [Ru2(bzpdc)(bipy)] (bzpdc = 4,4′-benzophenone dicarboxylate, bipy = 4,4′-bipyridine), revealing unique and highly relevant material features: In the 2D nanoporous framework, ruthenium paddle-wheel IBUs are mixed-valent and provide potential open metal sites. Coupled with the flexible behavior of the framework in the form of specific reversible structural transformations and selective gating upon adsorption of various guests, the material is thus ideally suited for sensing or catalytic applications.

ASJC Scopus subject areas

Cite this

Guest-Induced Flexibility in a Multifunctional Ruthenium-Based Metal-Organic Framework. / Hindricks, Karen D.J.; Bon, Volodymyr; Treske, Oliver et al.
In: Chemistry of materials, Vol. 36, No. 2, 23.01.2024, p. 657-665.

Research output: Contribution to journalArticleResearchpeer review

Hindricks, KDJ, Bon, V, Treske, O, Hannebauer, A, Schaate, A, Krysiak, Y & Kaskel, S 2024, 'Guest-Induced Flexibility in a Multifunctional Ruthenium-Based Metal-Organic Framework', Chemistry of materials, vol. 36, no. 2, pp. 657-665. https://doi.org/10.1021/acs.chemmater.3c01845
Hindricks, K. D. J., Bon, V., Treske, O., Hannebauer, A., Schaate, A., Krysiak, Y., & Kaskel, S. (2024). Guest-Induced Flexibility in a Multifunctional Ruthenium-Based Metal-Organic Framework. Chemistry of materials, 36(2), 657-665. https://doi.org/10.1021/acs.chemmater.3c01845
Hindricks KDJ, Bon V, Treske O, Hannebauer A, Schaate A, Krysiak Y et al. Guest-Induced Flexibility in a Multifunctional Ruthenium-Based Metal-Organic Framework. Chemistry of materials. 2024 Jan 23;36(2):657-665. Epub 2024 Jan 3. doi: 10.1021/acs.chemmater.3c01845
Hindricks, Karen D.J. ; Bon, Volodymyr ; Treske, Oliver et al. / Guest-Induced Flexibility in a Multifunctional Ruthenium-Based Metal-Organic Framework. In: Chemistry of materials. 2024 ; Vol. 36, No. 2. pp. 657-665.
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