Development of soft electrical conductive PDMS/CNT-Composites with extremely low CNT Content

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Marvin Christopher Vincenzo Omelan
  • Astrid Diekmann
  • Ulrich Giese

External Research Organisations

  • German Institute of Rubber Technology (DIK e.V.)
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Details

Original languageEnglish
Pages (from-to)22-30
Number of pages9
JournalKGK Kautschuk Gummi Kunststoffe
Volume73
Issue number7-8
Publication statusPublished - Aug 2020
Externally publishedYes

Abstract

In order to create electrical conductive polydimethylsiloxane/carbon nanotubecomposites with high flexibility, it is inevitable to minimize the filler content. To hold conductivity at a minimum of CNT content, an appropriate filler dispersion has to be realized. This was achieved by applying shear forces during compounding by modifying the mixing conditions to an optimum. The electrical percolation threshold is determined to be at 0.9 wt.% of CNTs. An optimized roll mill step enabled to further increase the conductivity and lead to an orientation of CNTs. By adding a high-dispersible silica, a significant shift of the percolation threshold towards 0.5 wt.% of CNTs was observed. Adding silica amounts of ≥ 15.0 wt.% resulted in an increase in stiffness and density, which is contradicting for the application in lightweight, soft and flexible components.

Keywords

    Dispersion, Flexibility, Percolation threshold, Planetary mixer, Shear forces

ASJC Scopus subject areas

Cite this

Development of soft electrical conductive PDMS/CNT-Composites with extremely low CNT Content. / Omelan, Marvin Christopher Vincenzo; Diekmann, Astrid; Giese, Ulrich.
In: KGK Kautschuk Gummi Kunststoffe, Vol. 73, No. 7-8, 08.2020, p. 22-30.

Research output: Contribution to journalArticleResearchpeer review

Omelan, Marvin Christopher Vincenzo ; Diekmann, Astrid ; Giese, Ulrich. / Development of soft electrical conductive PDMS/CNT-Composites with extremely low CNT Content. In: KGK Kautschuk Gummi Kunststoffe. 2020 ; Vol. 73, No. 7-8. pp. 22-30.
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abstract = "In order to create electrical conductive polydimethylsiloxane/carbon nanotubecomposites with high flexibility, it is inevitable to minimize the filler content. To hold conductivity at a minimum of CNT content, an appropriate filler dispersion has to be realized. This was achieved by applying shear forces during compounding by modifying the mixing conditions to an optimum. The electrical percolation threshold is determined to be at 0.9 wt.% of CNTs. An optimized roll mill step enabled to further increase the conductivity and lead to an orientation of CNTs. By adding a high-dispersible silica, a significant shift of the percolation threshold towards 0.5 wt.% of CNTs was observed. Adding silica amounts of ≥ 15.0 wt.% resulted in an increase in stiffness and density, which is contradicting for the application in lightweight, soft and flexible components.",
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