Details
| Original language | English |
|---|---|
| Pages (from-to) | 12121-12130 |
| Number of pages | 10 |
| Journal | Tetrahedron |
| Volume | 61 |
| Issue number | 51 |
| Publication status | Published - 26 Oct 2005 |
Abstract
The catalytic activity of a 2-pyridinealdoxime-based Pd(II)-complex covalently anchored via the oxime moiety to a glass/polymer composite material was evaluated in Suzuki-Miyaura cross-coupling reactions of aryl and heteroaryl halides, including arylchlorides, with aryl and heteroaryl boronic acids both under thermal as well as microwave irradiating conditions in water. The stability and reusability of this Pd-precatalyst is part of the present study.
Keywords
- Microwave conditions, Pd(II)-precatalyst, Suzuki-Miyaura cross-coupling reaction
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Biochemistry
- Pharmacology, Toxicology and Pharmaceutics(all)
- Drug Discovery
- Chemistry(all)
- Organic Chemistry
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In: Tetrahedron, Vol. 61, No. 51, 26.10.2005, p. 12121-12130.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Combining enabling techniques in organic synthesis
T2 - Solid-phase-assisted catalysis under microwave conditions using a stable Pd(II)-precatalyst
AU - Dawood, Kamal M.
AU - Kirschning, Andreas
N1 - Funding information: This work was supported by the DFG (Ki 397/6-1). K. M. Dawood is deeply indebted to the Alexander-von-Humboldt Foundation for granting him a postdoctoral fellowship (AGY1113724STP). We thank U. Kunz (Technical University of Clausthal) for providing us with polymer glass composite material.
PY - 2005/10/26
Y1 - 2005/10/26
N2 - The catalytic activity of a 2-pyridinealdoxime-based Pd(II)-complex covalently anchored via the oxime moiety to a glass/polymer composite material was evaluated in Suzuki-Miyaura cross-coupling reactions of aryl and heteroaryl halides, including arylchlorides, with aryl and heteroaryl boronic acids both under thermal as well as microwave irradiating conditions in water. The stability and reusability of this Pd-precatalyst is part of the present study.
AB - The catalytic activity of a 2-pyridinealdoxime-based Pd(II)-complex covalently anchored via the oxime moiety to a glass/polymer composite material was evaluated in Suzuki-Miyaura cross-coupling reactions of aryl and heteroaryl halides, including arylchlorides, with aryl and heteroaryl boronic acids both under thermal as well as microwave irradiating conditions in water. The stability and reusability of this Pd-precatalyst is part of the present study.
KW - Microwave conditions
KW - Pd(II)-precatalyst
KW - Suzuki-Miyaura cross-coupling reaction
UR - http://www.scopus.com/inward/record.url?scp=27944438117&partnerID=8YFLogxK
U2 - 10.1016/j.tet.2005.07.113
DO - 10.1016/j.tet.2005.07.113
M3 - Article
AN - SCOPUS:27944438117
VL - 61
SP - 12121
EP - 12130
JO - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
IS - 51
ER -