Characterization of clay and fine silt fractions of forest soils by standardized K/Ca sorption isotherms

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Authors

  • Stefan Dultz
  • Nestor Pesci
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Details

Original languageEnglish
Pages (from-to)83-89
Number of pages7
JournalJournal of Plant Nutrition and Soil Science
Volume163
Issue number1
Publication statusPublished - 2000

Abstract

For better comparison of selectivity characteristics of clay and fine silt fractions sorption isotherms standardized on the cation exchange capacity (CEC) are useful. Due to the effect of the CEC on the sorption isotherms, it is necessary to characterize the exchanging substance with regard to different ion selectivities with standardized potassium/calcium-(K/Ca) sorption isotherms. This procedure helps to complete the knowledge about the mineralogical composition, which is obtained by X-ray powder diffractometry. A Haplic Luvisol from boulder marl shows distinct differences in its K selectivity both between different particle size fractions and different horizons. This is partly due to the presence of smectites and vermiculites which are differently distributed within the particle size fractions. The increase of K selectivity with increasing particle diameter in the calcareous C horizon can be attributed to the marginal expansion of mica/illite by Ca2+ ions. The K selectivity of individual particle size fractions in different horizons of a Gleyic Cambisol from glacial sand shows major similarities. If pedogenic chlorite is formed, no changes in selectivity characteristics can be observed.

Keywords

    Cation exchange, Forest soils, Particle size fractions, Potassium, Selectivity, Standardized sorption isotherms

ASJC Scopus subject areas

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Characterization of clay and fine silt fractions of forest soils by standardized K/Ca sorption isotherms. / Dultz, Stefan; Pesci, Nestor.
In: Journal of Plant Nutrition and Soil Science, Vol. 163, No. 1, 2000, p. 83-89.

Research output: Contribution to journalArticleResearchpeer review

Dultz S, Pesci N. Characterization of clay and fine silt fractions of forest soils by standardized K/Ca sorption isotherms. Journal of Plant Nutrition and Soil Science. 2000;163(1):83-89. doi: 10.1002/(SICI)1522-2624(200002)163:1<83::AID-JPLN83>3.0.CO;2-Q
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abstract = "For better comparison of selectivity characteristics of clay and fine silt fractions sorption isotherms standardized on the cation exchange capacity (CEC) are useful. Due to the effect of the CEC on the sorption isotherms, it is necessary to characterize the exchanging substance with regard to different ion selectivities with standardized potassium/calcium-(K/Ca) sorption isotherms. This procedure helps to complete the knowledge about the mineralogical composition, which is obtained by X-ray powder diffractometry. A Haplic Luvisol from boulder marl shows distinct differences in its K selectivity both between different particle size fractions and different horizons. This is partly due to the presence of smectites and vermiculites which are differently distributed within the particle size fractions. The increase of K selectivity with increasing particle diameter in the calcareous C horizon can be attributed to the marginal expansion of mica/illite by Ca2+ ions. The K selectivity of individual particle size fractions in different horizons of a Gleyic Cambisol from glacial sand shows major similarities. If pedogenic chlorite is formed, no changes in selectivity characteristics can be observed.",
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AU - Pesci, Nestor

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PY - 2000

Y1 - 2000

N2 - For better comparison of selectivity characteristics of clay and fine silt fractions sorption isotherms standardized on the cation exchange capacity (CEC) are useful. Due to the effect of the CEC on the sorption isotherms, it is necessary to characterize the exchanging substance with regard to different ion selectivities with standardized potassium/calcium-(K/Ca) sorption isotherms. This procedure helps to complete the knowledge about the mineralogical composition, which is obtained by X-ray powder diffractometry. A Haplic Luvisol from boulder marl shows distinct differences in its K selectivity both between different particle size fractions and different horizons. This is partly due to the presence of smectites and vermiculites which are differently distributed within the particle size fractions. The increase of K selectivity with increasing particle diameter in the calcareous C horizon can be attributed to the marginal expansion of mica/illite by Ca2+ ions. The K selectivity of individual particle size fractions in different horizons of a Gleyic Cambisol from glacial sand shows major similarities. If pedogenic chlorite is formed, no changes in selectivity characteristics can be observed.

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