Details
Original language | English |
---|---|
Pages (from-to) | 83-89 |
Number of pages | 7 |
Journal | Journal of Plant Nutrition and Soil Science |
Volume | 163 |
Issue number | 1 |
Publication status | Published - 2000 |
Abstract
For better comparison of selectivity characteristics of clay and fine silt fractions sorption isotherms standardized on the cation exchange capacity (CEC) are useful. Due to the effect of the CEC on the sorption isotherms, it is necessary to characterize the exchanging substance with regard to different ion selectivities with standardized potassium/calcium-(K/Ca) sorption isotherms. This procedure helps to complete the knowledge about the mineralogical composition, which is obtained by X-ray powder diffractometry. A Haplic Luvisol from boulder marl shows distinct differences in its K selectivity both between different particle size fractions and different horizons. This is partly due to the presence of smectites and vermiculites which are differently distributed within the particle size fractions. The increase of K selectivity with increasing particle diameter in the calcareous C horizon can be attributed to the marginal expansion of mica/illite by Ca2+ ions. The K selectivity of individual particle size fractions in different horizons of a Gleyic Cambisol from glacial sand shows major similarities. If pedogenic chlorite is formed, no changes in selectivity characteristics can be observed.
Keywords
- Cation exchange, Forest soils, Particle size fractions, Potassium, Selectivity, Standardized sorption isotherms
ASJC Scopus subject areas
- Agricultural and Biological Sciences(all)
- Soil Science
- Agricultural and Biological Sciences(all)
- Plant Science
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In: Journal of Plant Nutrition and Soil Science, Vol. 163, No. 1, 2000, p. 83-89.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Characterization of clay and fine silt fractions of forest soils by standardized K/Ca sorption isotherms
AU - Dultz, Stefan
AU - Pesci, Nestor
N1 - Copyright: Copyright 2017 Elsevier B.V., All rights reserved.
PY - 2000
Y1 - 2000
N2 - For better comparison of selectivity characteristics of clay and fine silt fractions sorption isotherms standardized on the cation exchange capacity (CEC) are useful. Due to the effect of the CEC on the sorption isotherms, it is necessary to characterize the exchanging substance with regard to different ion selectivities with standardized potassium/calcium-(K/Ca) sorption isotherms. This procedure helps to complete the knowledge about the mineralogical composition, which is obtained by X-ray powder diffractometry. A Haplic Luvisol from boulder marl shows distinct differences in its K selectivity both between different particle size fractions and different horizons. This is partly due to the presence of smectites and vermiculites which are differently distributed within the particle size fractions. The increase of K selectivity with increasing particle diameter in the calcareous C horizon can be attributed to the marginal expansion of mica/illite by Ca2+ ions. The K selectivity of individual particle size fractions in different horizons of a Gleyic Cambisol from glacial sand shows major similarities. If pedogenic chlorite is formed, no changes in selectivity characteristics can be observed.
AB - For better comparison of selectivity characteristics of clay and fine silt fractions sorption isotherms standardized on the cation exchange capacity (CEC) are useful. Due to the effect of the CEC on the sorption isotherms, it is necessary to characterize the exchanging substance with regard to different ion selectivities with standardized potassium/calcium-(K/Ca) sorption isotherms. This procedure helps to complete the knowledge about the mineralogical composition, which is obtained by X-ray powder diffractometry. A Haplic Luvisol from boulder marl shows distinct differences in its K selectivity both between different particle size fractions and different horizons. This is partly due to the presence of smectites and vermiculites which are differently distributed within the particle size fractions. The increase of K selectivity with increasing particle diameter in the calcareous C horizon can be attributed to the marginal expansion of mica/illite by Ca2+ ions. The K selectivity of individual particle size fractions in different horizons of a Gleyic Cambisol from glacial sand shows major similarities. If pedogenic chlorite is formed, no changes in selectivity characteristics can be observed.
KW - Cation exchange
KW - Forest soils
KW - Particle size fractions
KW - Potassium
KW - Selectivity
KW - Standardized sorption isotherms
UR - http://www.scopus.com/inward/record.url?scp=23644456421&partnerID=8YFLogxK
U2 - 10.1002/(SICI)1522-2624(200002)163:1<83::AID-JPLN83>3.0.CO;2-Q
DO - 10.1002/(SICI)1522-2624(200002)163:1<83::AID-JPLN83>3.0.CO;2-Q
M3 - Article
AN - SCOPUS:23644456421
VL - 163
SP - 83
EP - 89
JO - Journal of Plant Nutrition and Soil Science
JF - Journal of Plant Nutrition and Soil Science
SN - 1436-8730
IS - 1
ER -