Details
| Original language | English |
|---|---|
| Article number | 130429 |
| Number of pages | 9 |
| Journal | FUEL |
| Volume | 359 |
| Early online date | 18 Nov 2023 |
| Publication status | Published - 1 Mar 2024 |
Abstract
In this investigation, spinel-type copper ferrites (CuFe2O4) at different calcination temperatures (600–900 °C) were produced using a facile citric acid-assisted sol–gel method. The crystal structure, morphology, optical, and electrical properties of the as synthesized photocatalysts were comprehensively characterized. XRD and UV–vis diffuse reflectance spectra (UV–vis (DRS)) showed that the phase structure and the band gap energy of the copper ferrite are strongly correlated to the applied calcination temperature. TEM results investigated that the copper ferrites calcined at higher temperatures presented large particle sizes and crystallized very well. In addition, the photocatalytic activity was tested for hydrogen production in the presence of methanol, with and without Pt nanoparticles as a cocatalyst. The results indicated that the CuFe2O4 annealed at 900 °C (CuF-900) has higher hydrogen production activity than photocatalysts calcined at lower temperatures in the presence and absence of Pt, which is mainly assigned to the higher crystallinity, and narrower bandgap energy. Moreover, this study explained in more detail the role of Pt nanoparticles in enhancing the photocatalytic activity of CuF-900. This work introduces a new direction of thinking for the tetragonal phase structure as an efficient photocatalyst for hydrogen production.
Keywords
- Copper ferrite, Crystallinity, Photocatalytic hydrogen production, Pt-cocatalyst, Tetragonal phase
ASJC Scopus subject areas
- Chemical Engineering(all)
- General Chemical Engineering
- Energy(all)
- Fuel Technology
- Energy(all)
- Energy Engineering and Power Technology
- Chemistry(all)
- Organic Chemistry
Sustainable Development Goals
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In: FUEL, Vol. 359, 130429, 01.03.2024.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - A simple sol–gel method for the synthesis of Pt co-catalyzed spinel-type CuFe2O4 for hydrogen production
T2 - the role of crystallinity and band gap energy
AU - Ismael, Mohammed
AU - Wark, Michael
PY - 2024/3/1
Y1 - 2024/3/1
N2 - In this investigation, spinel-type copper ferrites (CuFe2O4) at different calcination temperatures (600–900 °C) were produced using a facile citric acid-assisted sol–gel method. The crystal structure, morphology, optical, and electrical properties of the as synthesized photocatalysts were comprehensively characterized. XRD and UV–vis diffuse reflectance spectra (UV–vis (DRS)) showed that the phase structure and the band gap energy of the copper ferrite are strongly correlated to the applied calcination temperature. TEM results investigated that the copper ferrites calcined at higher temperatures presented large particle sizes and crystallized very well. In addition, the photocatalytic activity was tested for hydrogen production in the presence of methanol, with and without Pt nanoparticles as a cocatalyst. The results indicated that the CuFe2O4 annealed at 900 °C (CuF-900) has higher hydrogen production activity than photocatalysts calcined at lower temperatures in the presence and absence of Pt, which is mainly assigned to the higher crystallinity, and narrower bandgap energy. Moreover, this study explained in more detail the role of Pt nanoparticles in enhancing the photocatalytic activity of CuF-900. This work introduces a new direction of thinking for the tetragonal phase structure as an efficient photocatalyst for hydrogen production.
AB - In this investigation, spinel-type copper ferrites (CuFe2O4) at different calcination temperatures (600–900 °C) were produced using a facile citric acid-assisted sol–gel method. The crystal structure, morphology, optical, and electrical properties of the as synthesized photocatalysts were comprehensively characterized. XRD and UV–vis diffuse reflectance spectra (UV–vis (DRS)) showed that the phase structure and the band gap energy of the copper ferrite are strongly correlated to the applied calcination temperature. TEM results investigated that the copper ferrites calcined at higher temperatures presented large particle sizes and crystallized very well. In addition, the photocatalytic activity was tested for hydrogen production in the presence of methanol, with and without Pt nanoparticles as a cocatalyst. The results indicated that the CuFe2O4 annealed at 900 °C (CuF-900) has higher hydrogen production activity than photocatalysts calcined at lower temperatures in the presence and absence of Pt, which is mainly assigned to the higher crystallinity, and narrower bandgap energy. Moreover, this study explained in more detail the role of Pt nanoparticles in enhancing the photocatalytic activity of CuF-900. This work introduces a new direction of thinking for the tetragonal phase structure as an efficient photocatalyst for hydrogen production.
KW - Copper ferrite
KW - Crystallinity
KW - Photocatalytic hydrogen production
KW - Pt-cocatalyst
KW - Tetragonal phase
UR - http://www.scopus.com/inward/record.url?scp=85177593393&partnerID=8YFLogxK
U2 - 10.1016/j.fuel.2023.130429
DO - 10.1016/j.fuel.2023.130429
M3 - Article
AN - SCOPUS:85177593393
VL - 359
JO - FUEL
JF - FUEL
SN - 0016-2361
M1 - 130429
ER -