Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • Igor Milanović
  • Sanja Milošević Govedarović
  • Miodrag Lukić
  • Zoran Jovanović
  • Jelena Rmuš
  • Andela Mitrović Rajić
  • Jasmina Grbović Novaković
  • Sandra Kurko

Organisationseinheiten

Externe Organisationen

  • University of Belgrade
  • Serbian Academy of Sciences and Arts (SANU)
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Details

OriginalspracheEnglisch
Seiten (von - bis)259-266
Seitenumfang8
FachzeitschriftProcessing and Application of Ceramics
Jahrgang16
Ausgabenummer3
PublikationsstatusVeröffentlicht - 2022

Abstract

LiAlH4 was modified by mechanical milling and with the addition of 5 wt.% Fe2O3 in order to improve its hydrogen desorption properties. The composite was milled for 1, 3, 5, 7 or 15 min, and depending on the milling time, various phenomena took place. Up to a milling time of 5 min, the particle size of the composite decreases. Further milling leads to the particles agglomeration reaching the size of the starting material after 15 min. Moreover, the mechanical milling process leads to the transformation of AlH4– to AlH63 – structure as a result of partial hydrogen desorption. Hydrogen desorption during the milling is the most pronounced in the sample milled for 15 min, so this sample has only one hydrogen desorption peak in the temperature-programmed desorption measurements. Mechanical milling with the addition of Fe2O3 for up to 15 min improves LiAlH4 hydrogen desorption properties as hydrogen desorption temperature and apparent activation energies decrease.

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Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites. / Milanović, Igor; Govedarović, Sanja Milošević; Lukić, Miodrag et al.
in: Processing and Application of Ceramics, Jahrgang 16, Nr. 3, 2022, S. 259-266.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Milanović, I, Govedarović, SM, Lukić, M, Jovanović, Z, Rmuš, J, Rajić, AM, Novaković, JG & Kurko, S 2022, 'Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites', Processing and Application of Ceramics, Jg. 16, Nr. 3, S. 259-266. https://doi.org/10.2298/PAC2203259M
Milanović, I., Govedarović, S. M., Lukić, M., Jovanović, Z., Rmuš, J., Rajić, A. M., Novaković, J. G., & Kurko, S. (2022). Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites. Processing and Application of Ceramics, 16(3), 259-266. https://doi.org/10.2298/PAC2203259M
Milanović I, Govedarović SM, Lukić M, Jovanović Z, Rmuš J, Rajić AM et al. Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites. Processing and Application of Ceramics. 2022;16(3):259-266. doi: 10.2298/PAC2203259M
Milanović, Igor ; Govedarović, Sanja Milošević ; Lukić, Miodrag et al. / Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites. in: Processing and Application of Ceramics. 2022 ; Jahrgang 16, Nr. 3. S. 259-266.
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abstract = "LiAlH4 was modified by mechanical milling and with the addition of 5 wt.% Fe2O3 in order to improve its hydrogen desorption properties. The composite was milled for 1, 3, 5, 7 or 15 min, and depending on the milling time, various phenomena took place. Up to a milling time of 5 min, the particle size of the composite decreases. Further milling leads to the particles agglomeration reaching the size of the starting material after 15 min. Moreover, the mechanical milling process leads to the transformation of AlH4– to AlH63 – structure as a result of partial hydrogen desorption. Hydrogen desorption during the milling is the most pronounced in the sample milled for 15 min, so this sample has only one hydrogen desorption peak in the temperature-programmed desorption measurements. Mechanical milling with the addition of Fe2O3 for up to 15 min improves LiAlH4 hydrogen desorption properties as hydrogen desorption temperature and apparent activation energies decrease.",
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author = "Igor Milanovi{\'c} and Govedarovi{\'c}, {Sanja Milo{\v s}evi{\'c}} and Miodrag Luki{\'c} and Zoran Jovanovi{\'c} and Jelena Rmu{\v s} and Raji{\'c}, {Andela Mitrovi{\'c}} and Novakovi{\'c}, {Jasmina Grbovi{\'c}} and Sandra Kurko",
note = "Funding Information: This research was financially supported by The Ministry of Education, Science and Technology of the Republic of Serbia through the Program of institutional financing ",
year = "2022",
doi = "10.2298/PAC2203259M",
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volume = "16",
pages = "259--266",
journal = "Processing and Application of Ceramics",
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Download

TY - JOUR

T1 - Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites

AU - Milanović, Igor

AU - Govedarović, Sanja Milošević

AU - Lukić, Miodrag

AU - Jovanović, Zoran

AU - Rmuš, Jelena

AU - Rajić, Andela Mitrović

AU - Novaković, Jasmina Grbović

AU - Kurko, Sandra

N1 - Funding Information: This research was financially supported by The Ministry of Education, Science and Technology of the Republic of Serbia through the Program of institutional financing

PY - 2022

Y1 - 2022

N2 - LiAlH4 was modified by mechanical milling and with the addition of 5 wt.% Fe2O3 in order to improve its hydrogen desorption properties. The composite was milled for 1, 3, 5, 7 or 15 min, and depending on the milling time, various phenomena took place. Up to a milling time of 5 min, the particle size of the composite decreases. Further milling leads to the particles agglomeration reaching the size of the starting material after 15 min. Moreover, the mechanical milling process leads to the transformation of AlH4– to AlH63 – structure as a result of partial hydrogen desorption. Hydrogen desorption during the milling is the most pronounced in the sample milled for 15 min, so this sample has only one hydrogen desorption peak in the temperature-programmed desorption measurements. Mechanical milling with the addition of Fe2O3 for up to 15 min improves LiAlH4 hydrogen desorption properties as hydrogen desorption temperature and apparent activation energies decrease.

AB - LiAlH4 was modified by mechanical milling and with the addition of 5 wt.% Fe2O3 in order to improve its hydrogen desorption properties. The composite was milled for 1, 3, 5, 7 or 15 min, and depending on the milling time, various phenomena took place. Up to a milling time of 5 min, the particle size of the composite decreases. Further milling leads to the particles agglomeration reaching the size of the starting material after 15 min. Moreover, the mechanical milling process leads to the transformation of AlH4– to AlH63 – structure as a result of partial hydrogen desorption. Hydrogen desorption during the milling is the most pronounced in the sample milled for 15 min, so this sample has only one hydrogen desorption peak in the temperature-programmed desorption measurements. Mechanical milling with the addition of Fe2O3 for up to 15 min improves LiAlH4 hydrogen desorption properties as hydrogen desorption temperature and apparent activation energies decrease.

KW - composites

KW - hydrides

KW - hydrogen storage

KW - kinetics

KW - mechanochemical synthesis

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DO - 10.2298/PAC2203259M

M3 - Article

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VL - 16

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EP - 266

JO - Processing and Application of Ceramics

JF - Processing and Application of Ceramics

SN - 1820-6131

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