The effect of high polaron concentration on the polaron transport in NbO2.5-x: Optical and electrical properties

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Authors

  • C. Ruscher
  • E. Salje
  • A. Hussain

Research Organisations

External Research Organisations

  • University of Cambridge
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Details

Original languageEnglish
Pages (from-to)3737-3749
Number of pages13
JournalJournal of Physics C: Solid State Physics
Volume21
Issue number20
Publication statusPublished - 20 Jul 1988

Abstract

The electrical conductivity and optical absorption of NbO2.5-x (0.005<x<0.08) are described by polaron ground states. Correlated hopping and polaronic absorption of weakly disordered systems are observed in the regime of low carrier concentration (x<0.05). Bipolarons and single polarons are both stable in this regime. At higher carrier concentrations, quasi-metallic conductivity and saturated polaron concentrations are described as being due to the superposition of polaron groundstates and quasi-free electrons. The saturation concentration yields a critical distance of about 10 AA between polarons. The threshold value of x=0.05 is related to the geometrical properties of the NbO2.5-x structures.

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The effect of high polaron concentration on the polaron transport in NbO2.5-x: Optical and electrical properties. / Ruscher, C.; Salje, E.; Hussain, A.
In: Journal of Physics C: Solid State Physics, Vol. 21, No. 20, 20.07.1988, p. 3737-3749.

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