Anomalous electrical transport in SnSe2 nanosheets: Role of thickness and surface defect states

Research output: Contribution to journalArticleResearchpeer review

Authors

Research Organisations

External Research Organisations

  • Indian Institute of Technology Indore (IITI)
View graph of relations

Details

Original languageEnglish
Article number235401
JournalPhysical Review B
Volume112
Issue number23
Publication statusPublished - 15 Dec 2025

Abstract

This work examines the influence of thickness on the electrical transport properties of mechanically exfoliated two-dimensional SnSe2 nanosheets, derived from the bulk single crystal. Contrary to the conventional trend observed in two-dimensional systems, we find a semiconducting to metallic resistivity behavior with decreasing thickness. The analysis of low-temperature conduction indicates an increased density of states at the Fermi level with decreasing thickness, which is further corroborated by gate bias-dependent conductance measurement. The enhanced conductivity in thinner flake is attributed to the n-type doping arising from surface defect states. The presence and evolution of these defect states with thickness are probed by thickness-dependent room-temperature Raman spectroscopy. Our study provides insights into the thickness-dependent electronic transport mechanism of SnSe2 and the crucial role of defect states in governing the observed conductivity behavior.

ASJC Scopus subject areas

Cite this

Anomalous electrical transport in SnSe2 nanosheets: Role of thickness and surface defect states. / Lakhara, Aarti; Thole, Lars; Haug, Rolf J. et al.
In: Physical Review B, Vol. 112, No. 23, 235401, 15.12.2025.

Research output: Contribution to journalArticleResearchpeer review

Lakhara A, Thole L, Haug RJ, Bhobe PA. Anomalous electrical transport in SnSe2 nanosheets: Role of thickness and surface defect states. Physical Review B. 2025 Dec 15;112(23):235401. doi: 10.1103/hrp5-pts7
Download
@article{ba4b8f1fe8d1413e98cbdab698f153ef,
title = "Anomalous electrical transport in SnSe2 nanosheets: Role of thickness and surface defect states",
abstract = "This work examines the influence of thickness on the electrical transport properties of mechanically exfoliated two-dimensional SnSe2 nanosheets, derived from the bulk single crystal. Contrary to the conventional trend observed in two-dimensional systems, we find a semiconducting to metallic resistivity behavior with decreasing thickness. The analysis of low-temperature conduction indicates an increased density of states at the Fermi level with decreasing thickness, which is further corroborated by gate bias-dependent conductance measurement. The enhanced conductivity in thinner flake is attributed to the n-type doping arising from surface defect states. The presence and evolution of these defect states with thickness are probed by thickness-dependent room-temperature Raman spectroscopy. Our study provides insights into the thickness-dependent electronic transport mechanism of SnSe2 and the crucial role of defect states in governing the observed conductivity behavior.",
author = "Aarti Lakhara and Lars Thole and Haug, {Rolf J.} and Bhobe, {P. A.}",
note = "Publisher Copyright: {\textcopyright} (2025), (American Physical Society). All rights reserved.",
year = "2025",
month = dec,
day = "15",
doi = "10.1103/hrp5-pts7",
language = "English",
volume = "112",
journal = "Physical Review B",
issn = "2469-9950",
publisher = "American Physical Society",
number = "23",

}

Download

TY - JOUR

T1 - Anomalous electrical transport in SnSe2 nanosheets

T2 - Role of thickness and surface defect states

AU - Lakhara, Aarti

AU - Thole, Lars

AU - Haug, Rolf J.

AU - Bhobe, P. A.

N1 - Publisher Copyright: © (2025), (American Physical Society). All rights reserved.

PY - 2025/12/15

Y1 - 2025/12/15

N2 - This work examines the influence of thickness on the electrical transport properties of mechanically exfoliated two-dimensional SnSe2 nanosheets, derived from the bulk single crystal. Contrary to the conventional trend observed in two-dimensional systems, we find a semiconducting to metallic resistivity behavior with decreasing thickness. The analysis of low-temperature conduction indicates an increased density of states at the Fermi level with decreasing thickness, which is further corroborated by gate bias-dependent conductance measurement. The enhanced conductivity in thinner flake is attributed to the n-type doping arising from surface defect states. The presence and evolution of these defect states with thickness are probed by thickness-dependent room-temperature Raman spectroscopy. Our study provides insights into the thickness-dependent electronic transport mechanism of SnSe2 and the crucial role of defect states in governing the observed conductivity behavior.

AB - This work examines the influence of thickness on the electrical transport properties of mechanically exfoliated two-dimensional SnSe2 nanosheets, derived from the bulk single crystal. Contrary to the conventional trend observed in two-dimensional systems, we find a semiconducting to metallic resistivity behavior with decreasing thickness. The analysis of low-temperature conduction indicates an increased density of states at the Fermi level with decreasing thickness, which is further corroborated by gate bias-dependent conductance measurement. The enhanced conductivity in thinner flake is attributed to the n-type doping arising from surface defect states. The presence and evolution of these defect states with thickness are probed by thickness-dependent room-temperature Raman spectroscopy. Our study provides insights into the thickness-dependent electronic transport mechanism of SnSe2 and the crucial role of defect states in governing the observed conductivity behavior.

UR - http://www.scopus.com/inward/record.url?scp=105027385095&partnerID=8YFLogxK

U2 - 10.1103/hrp5-pts7

DO - 10.1103/hrp5-pts7

M3 - Article

AN - SCOPUS:105027385095

VL - 112

JO - Physical Review B

JF - Physical Review B

SN - 2469-9950

IS - 23

M1 - 235401

ER -

By the same author(s)