Optimization of Photolithographic Fabrication of Photonic Crystals and their Use in High Efficiency Solar Cells

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autorschaft

  • Leon Salomon
  • Michael Rienäcker
  • Yevgeniya Larionova
  • Alexej Haller
  • Sarah Spätlich
  • Robby Peibst
  • Jan Krügener

Externe Organisationen

  • Karlsruher Institut für Technologie (KIT)
  • Institut für Solarenergieforschung GmbH (ISFH)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Aufsatznummere202500483
FachzeitschriftSolar RRL
Jahrgang9
Ausgabenummer22
PublikationsstatusVeröffentlicht - 24 Nov. 2025

Abstract

In this work we present an optimized process for the photolithographic fabrication of inverted pyramid photonic crystals (PC) with 3.1 µm periodicity on Si(001)-substrates to improve the light trapping in single junction solar cells. Anisotropic alkaline etch was used to form the pyramids with (111)-sidewalls using partial surface masking with lithographically structured SiO2. Ridge widths between the pyramids down to (150 ± 50) nm were achieved, while ensuring a yield of multiple (2 × 2) cm2 areas per wafer sample. After deposition of an antireflection stack consisting of AlOx, SiNy, and SiOz with different thickness optimizations a weighted reflection approaching that of a random pyramid reference sample could be shown. We demonstrate a path length enhancement of 25 at a wavelength of 1200 nm for our cell with PCs. This is en par with but not superior to the respective value for the reference sample with random pyramids, and still below the Lambertian limit. Furthermore, we present the first POLO2-IBC (interdigitated back contact) solar cells with such photonic crystals on the front sides. These solar cells feature a power conversion efficiency of 22.9%.

ASJC Scopus Sachgebiete

Zitieren

Optimization of Photolithographic Fabrication of Photonic Crystals and their Use in High Efficiency Solar Cells. / Salomon, Leon; Rienäcker, Michael; Larionova, Yevgeniya et al.
in: Solar RRL, Jahrgang 9, Nr. 22, e202500483, 24.11.2025.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Salomon, L, Rienäcker, M, Larionova, Y, Haller, A, Spätlich, S, Peibst, R & Krügener, J 2025, 'Optimization of Photolithographic Fabrication of Photonic Crystals and their Use in High Efficiency Solar Cells', Solar RRL, Jg. 9, Nr. 22, e202500483. https://doi.org/10.1002/solr.202500483
Salomon, L., Rienäcker, M., Larionova, Y., Haller, A., Spätlich, S., Peibst, R., & Krügener, J. (2025). Optimization of Photolithographic Fabrication of Photonic Crystals and their Use in High Efficiency Solar Cells. Solar RRL, 9(22), Artikel e202500483. https://doi.org/10.1002/solr.202500483
Salomon L, Rienäcker M, Larionova Y, Haller A, Spätlich S, Peibst R et al. Optimization of Photolithographic Fabrication of Photonic Crystals and their Use in High Efficiency Solar Cells. Solar RRL. 2025 Nov 24;9(22):e202500483. doi: 10.1002/solr.202500483
Salomon, Leon ; Rienäcker, Michael ; Larionova, Yevgeniya et al. / Optimization of Photolithographic Fabrication of Photonic Crystals and their Use in High Efficiency Solar Cells. in: Solar RRL. 2025 ; Jahrgang 9, Nr. 22.
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abstract = "In this work we present an optimized process for the photolithographic fabrication of inverted pyramid photonic crystals (PC) with 3.1 µm periodicity on Si(001)-substrates to improve the light trapping in single junction solar cells. Anisotropic alkaline etch was used to form the pyramids with (111)-sidewalls using partial surface masking with lithographically structured SiO2. Ridge widths between the pyramids down to (150 ± 50) nm were achieved, while ensuring a yield of multiple (2 × 2) cm2 areas per wafer sample. After deposition of an antireflection stack consisting of AlOx, SiNy, and SiOz with different thickness optimizations a weighted reflection approaching that of a random pyramid reference sample could be shown. We demonstrate a path length enhancement of 25 at a wavelength of 1200 nm for our cell with PCs. This is en par with but not superior to the respective value for the reference sample with random pyramids, and still below the Lambertian limit. Furthermore, we present the first POLO2-IBC (interdigitated back contact) solar cells with such photonic crystals on the front sides. These solar cells feature a power conversion efficiency of 22.9%.",
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AU - Salomon, Leon

AU - Rienäcker, Michael

AU - Larionova, Yevgeniya

AU - Haller, Alexej

AU - Spätlich, Sarah

AU - Peibst, Robby

AU - Krügener, Jan

N1 - Publisher Copyright: © 2025 The Author(s). Solar RRL published by Wiley-VCH GmbH.

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N2 - In this work we present an optimized process for the photolithographic fabrication of inverted pyramid photonic crystals (PC) with 3.1 µm periodicity on Si(001)-substrates to improve the light trapping in single junction solar cells. Anisotropic alkaline etch was used to form the pyramids with (111)-sidewalls using partial surface masking with lithographically structured SiO2. Ridge widths between the pyramids down to (150 ± 50) nm were achieved, while ensuring a yield of multiple (2 × 2) cm2 areas per wafer sample. After deposition of an antireflection stack consisting of AlOx, SiNy, and SiOz with different thickness optimizations a weighted reflection approaching that of a random pyramid reference sample could be shown. We demonstrate a path length enhancement of 25 at a wavelength of 1200 nm for our cell with PCs. This is en par with but not superior to the respective value for the reference sample with random pyramids, and still below the Lambertian limit. Furthermore, we present the first POLO2-IBC (interdigitated back contact) solar cells with such photonic crystals on the front sides. These solar cells feature a power conversion efficiency of 22.9%.

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KW - interdigitated back contact solar cells

KW - inverted pyramids

KW - photolithography

KW - photonic crystals

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