Influence of an Argon/Silane Atmosphere on the Temperature of a Thermal Plasma

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OriginalspracheEnglisch
FachzeitschriftAdvanced engineering materials
PublikationsstatusAngenommen/Im Druck - 2026

Abstract

One promising approach to keep the residual oxygen level in welding at extremely low levels is to add monosilane to the argon shielding gas. However, its effect on the plasma itself is not clear, and thus this study examines the influence of a silane-doped argon atmosphere on the chemical components and temperature within a nontransferring, thermal argon plasma in comparison to an atmosphere of pure argon and air. For this purpose, the emitted radiation of the plasma was analyzed using optical emission spectroscopy. The spectra show that the Ar I lines are most prominent in all atmospheres. Compared to the air atmosphere, the plasma in the argon atmosphere exhibits a stronger H I line and an OH emission band. A slight doping of the argon atmosphere with silane (0.01 vol.%) leads to strongly pronounced Si I and H I lines and a clearly recognizable H2 emission band. The high amount of free electrons resulting from the stepwise ionization and dissociation of the silane molecule leads to an increase in plasma temperature from about 7,600 to 9,000 K.

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Influence of an Argon/Silane Atmosphere on the Temperature of a Thermal Plasma. / Kreie, Lena; Kramer, David; Scheithauer, Thomas et al.
in: Advanced engineering materials, 2026.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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title = "Influence of an Argon/Silane Atmosphere on the Temperature of a Thermal Plasma",
abstract = "One promising approach to keep the residual oxygen level in welding at extremely low levels is to add monosilane to the argon shielding gas. However, its effect on the plasma itself is not clear, and thus this study examines the influence of a silane-doped argon atmosphere on the chemical components and temperature within a nontransferring, thermal argon plasma in comparison to an atmosphere of pure argon and air. For this purpose, the emitted radiation of the plasma was analyzed using optical emission spectroscopy. The spectra show that the Ar I lines are most prominent in all atmospheres. Compared to the air atmosphere, the plasma in the argon atmosphere exhibits a stronger H I line and an OH emission band. A slight doping of the argon atmosphere with silane (0.01 vol.%) leads to strongly pronounced Si I and H I lines and a clearly recognizable H2 emission band. The high amount of free electrons resulting from the stepwise ionization and dissociation of the silane molecule leads to an increase in plasma temperature from about 7,600 to 9,000 K.",
keywords = "Boltzmann plot, optical emission spectroscopy, oxygen-free production, plasma temperature, thermal plasma",
author = "Lena Kreie and David Kramer and Thomas Scheithauer and Maier, {Hans J{\"u}rgen} and Thomas Hassel",
note = "Publisher Copyright: {\textcopyright} 2026 The Author(s). Advanced Engineering Materials published by Wiley-VCH GmbH.",
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TY - JOUR

T1 - Influence of an Argon/Silane Atmosphere on the Temperature of a Thermal Plasma

AU - Kreie, Lena

AU - Kramer, David

AU - Scheithauer, Thomas

AU - Maier, Hans Jürgen

AU - Hassel, Thomas

N1 - Publisher Copyright: © 2026 The Author(s). Advanced Engineering Materials published by Wiley-VCH GmbH.

PY - 2026

Y1 - 2026

N2 - One promising approach to keep the residual oxygen level in welding at extremely low levels is to add monosilane to the argon shielding gas. However, its effect on the plasma itself is not clear, and thus this study examines the influence of a silane-doped argon atmosphere on the chemical components and temperature within a nontransferring, thermal argon plasma in comparison to an atmosphere of pure argon and air. For this purpose, the emitted radiation of the plasma was analyzed using optical emission spectroscopy. The spectra show that the Ar I lines are most prominent in all atmospheres. Compared to the air atmosphere, the plasma in the argon atmosphere exhibits a stronger H I line and an OH emission band. A slight doping of the argon atmosphere with silane (0.01 vol.%) leads to strongly pronounced Si I and H I lines and a clearly recognizable H2 emission band. The high amount of free electrons resulting from the stepwise ionization and dissociation of the silane molecule leads to an increase in plasma temperature from about 7,600 to 9,000 K.

AB - One promising approach to keep the residual oxygen level in welding at extremely low levels is to add monosilane to the argon shielding gas. However, its effect on the plasma itself is not clear, and thus this study examines the influence of a silane-doped argon atmosphere on the chemical components and temperature within a nontransferring, thermal argon plasma in comparison to an atmosphere of pure argon and air. For this purpose, the emitted radiation of the plasma was analyzed using optical emission spectroscopy. The spectra show that the Ar I lines are most prominent in all atmospheres. Compared to the air atmosphere, the plasma in the argon atmosphere exhibits a stronger H I line and an OH emission band. A slight doping of the argon atmosphere with silane (0.01 vol.%) leads to strongly pronounced Si I and H I lines and a clearly recognizable H2 emission band. The high amount of free electrons resulting from the stepwise ionization and dissociation of the silane molecule leads to an increase in plasma temperature from about 7,600 to 9,000 K.

KW - Boltzmann plot

KW - optical emission spectroscopy

KW - oxygen-free production

KW - plasma temperature

KW - thermal plasma

UR - http://www.scopus.com/inward/record.url?scp=105029342768&partnerID=8YFLogxK

U2 - 10.1002/adem.202502558

DO - 10.1002/adem.202502558

M3 - Article

AN - SCOPUS:105029342768

JO - Advanced engineering materials

JF - Advanced engineering materials

SN - 1438-1656

ER -

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