Details
Originalsprache | Englisch |
---|---|
Seiten (von - bis) | 4754-4759 |
Seitenumfang | 6 |
Fachzeitschrift | Inorganica chimica acta |
Jahrgang | 362 |
Ausgabenummer | 13 |
Publikationsstatus | Veröffentlicht - 15 Okt. 2009 |
Abstract
Synthesis and structure of dinuclear complexes [{FeIII(L5)}b{FeIII(L5)}](BPh4)2, where L5 is a pentadentate Schiff-base ligand, b is a bidentate N-oxide bridging ligand based on bipyridine, is reported. Magnetic behavior is investigated in terms of the magnetic susceptibility, magnetization, and Mössbauer spectroscopy revealing that the complexes are high-spin over the whole temperature region.
ASJC Scopus Sachgebiete
- Chemie (insg.)
- Physikalische und Theoretische Chemie
- Chemie (insg.)
- Anorganische Chemie
- Werkstoffwissenschaften (insg.)
- Werkstoffchemie
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in: Inorganica chimica acta, Jahrgang 362, Nr. 13, 15.10.2009, S. 4754-4759.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
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TY - JOUR
T1 - High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands
AU - Nemec, Ivan
AU - Boča, Roman
AU - Gembický, Milan
AU - Dlháň, Lubor
AU - Herchel, Radovan
AU - Renz, Franz
N1 - Funding Information: The authors would like to acknowledge Prof. Philip Coppens for providing diffractometer measurement time and to Prof. Jozef Kožíšek for preliminary X-ray experiments. Grant agencies and project sponsors (Slovakia: VEGA 1/0213/08, APVV 0006-07, COST-0006-06, VVCE-0004-07; Czech Republic: MSM6198959218, KAN115600801; USA: NSF CHE 0236317(PC); Germany: Leibniz University (ZFM)) are acknowledged for the financial support.
PY - 2009/10/15
Y1 - 2009/10/15
N2 - Synthesis and structure of dinuclear complexes [{FeIII(L5)}b{FeIII(L5)}](BPh4)2, where L5 is a pentadentate Schiff-base ligand, b is a bidentate N-oxide bridging ligand based on bipyridine, is reported. Magnetic behavior is investigated in terms of the magnetic susceptibility, magnetization, and Mössbauer spectroscopy revealing that the complexes are high-spin over the whole temperature region.
AB - Synthesis and structure of dinuclear complexes [{FeIII(L5)}b{FeIII(L5)}](BPh4)2, where L5 is a pentadentate Schiff-base ligand, b is a bidentate N-oxide bridging ligand based on bipyridine, is reported. Magnetic behavior is investigated in terms of the magnetic susceptibility, magnetization, and Mössbauer spectroscopy revealing that the complexes are high-spin over the whole temperature region.
KW - Iron(III) complex
KW - Magnetism
KW - Mössbauer spectroscopy
KW - N-oxide ligands
KW - Schiff-base ligands
KW - Structure
UR - http://www.scopus.com/inward/record.url?scp=70349240239&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2009.06.057
DO - 10.1016/j.ica.2009.06.057
M3 - Article
AN - SCOPUS:70349240239
VL - 362
SP - 4754
EP - 4759
JO - Inorganica chimica acta
JF - Inorganica chimica acta
SN - 0020-1693
IS - 13
ER -