Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 10321-10328 |
| Seitenumfang | 8 |
| Fachzeitschrift | Journal of Physical Chemistry C |
| Jahrgang | 129 |
| Ausgabenummer | 22 |
| Frühes Online-Datum | 27 Mai 2025 |
| Publikationsstatus | Veröffentlicht - 5 Juni 2025 |
Abstract
Volatile organic compounds (VOCs) pose health risks, leading to a growing focus on adsorption-based removal and sensing methods for these compounds. Metal-organic frameworks (MOFs), known for their high porosity and tunable structures, have emerged as promising adsorbents. Among them, UiO-66 stands out due to its exceptional chemical and thermal stability and its ability to adsorb a broad range of VOCs with diverse chemical properties. While prior research has focused on defect engineering to enhance VOC adsorption in UiO-66, the potential of functionalized linkers in UiO-66 derivatives tailored for specific VOCs remains underexplored. This study examines vapor adsorption in five functionalized UiO-66 derivatives using static vapor adsorption measurements and simulation methods analyzing chemically diverse VOCs, including alkanes, aromatics, and alcohols. The results show that functionalization enhances affinity for polar VOCs at low pressure, highlighting the potential of linker functionalization for VOC capture and sensing applications, particularly in environments where VOCs concentrations are low.
ASJC Scopus Sachgebiete
- Werkstoffwissenschaften (insg.)
- Elektronische, optische und magnetische Materialien
- Energie (insg.)
- Allgemeine Energie
- Chemie (insg.)
- Physikalische und Theoretische Chemie
- Werkstoffwissenschaften (insg.)
- Oberflächen, Beschichtungen und Folien
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in: Journal of Physical Chemistry C, Jahrgang 129, Nr. 22, 05.06.2025, S. 10321-10328.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Adsorption of Volatile Organic Compounds in Functionalized UiO-66
T2 - Insights from Experiment and Simulation
AU - Hannebauer, Adrian
AU - Rohloff, Erik
AU - Schneider, Andreas M.
AU - Schaate, Andreas
N1 - Publisher Copyright: © 2025 The Authors. Published by American Chemical Society.
PY - 2025/6/5
Y1 - 2025/6/5
N2 - Volatile organic compounds (VOCs) pose health risks, leading to a growing focus on adsorption-based removal and sensing methods for these compounds. Metal-organic frameworks (MOFs), known for their high porosity and tunable structures, have emerged as promising adsorbents. Among them, UiO-66 stands out due to its exceptional chemical and thermal stability and its ability to adsorb a broad range of VOCs with diverse chemical properties. While prior research has focused on defect engineering to enhance VOC adsorption in UiO-66, the potential of functionalized linkers in UiO-66 derivatives tailored for specific VOCs remains underexplored. This study examines vapor adsorption in five functionalized UiO-66 derivatives using static vapor adsorption measurements and simulation methods analyzing chemically diverse VOCs, including alkanes, aromatics, and alcohols. The results show that functionalization enhances affinity for polar VOCs at low pressure, highlighting the potential of linker functionalization for VOC capture and sensing applications, particularly in environments where VOCs concentrations are low.
AB - Volatile organic compounds (VOCs) pose health risks, leading to a growing focus on adsorption-based removal and sensing methods for these compounds. Metal-organic frameworks (MOFs), known for their high porosity and tunable structures, have emerged as promising adsorbents. Among them, UiO-66 stands out due to its exceptional chemical and thermal stability and its ability to adsorb a broad range of VOCs with diverse chemical properties. While prior research has focused on defect engineering to enhance VOC adsorption in UiO-66, the potential of functionalized linkers in UiO-66 derivatives tailored for specific VOCs remains underexplored. This study examines vapor adsorption in five functionalized UiO-66 derivatives using static vapor adsorption measurements and simulation methods analyzing chemically diverse VOCs, including alkanes, aromatics, and alcohols. The results show that functionalization enhances affinity for polar VOCs at low pressure, highlighting the potential of linker functionalization for VOC capture and sensing applications, particularly in environments where VOCs concentrations are low.
UR - http://www.scopus.com/inward/record.url?scp=105005938208&partnerID=8YFLogxK
U2 - 10.1021/acs.jpcc.5c01987
DO - 10.1021/acs.jpcc.5c01987
M3 - Article
AN - SCOPUS:105005938208
VL - 129
SP - 10321
EP - 10328
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 22
ER -